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Organic and Petrochem. Synthesis

Kashkovskij Vladimir Ilyich,
Candidate of chemical sciences, scientific researcher.
Contact information:
Adress: Kiev, Kharkivske Shosse, 50
Phone / fax: 559 70 60
Scientific direction of
the subdivision work:
The main scientific direction of the department ¹8 is an investigation
of the metathesysis and sometathesysis of different olefines, including
olefines with functional groups and its use in the processes of carbohydrates
interconversions; the search and investigation of the effectivity of action
of a new catalytic systems in the metathesysis and sometathesysis reactions,
investigation of the influence of different factors on its passing; clarification
of the possibility to combine the oligomerization and isomerization reactions
of the lower olefines in one technological cycle with subsiquent metathesysis
and somethesysis of the products obtained.
The works directed on development
of the technological methods of sterilization of a toxic industrial wastes
of different origin are realized in our department. The investigations
developed are based on the approaches concerning with a possibility of
the transformations of such wastes into matherials safe for the environment
or their use as secondary base for the obtaining of valuable products.
Recently the experimental - industrial technology was created to neutralize
high - concentrated toxic remain which was formed after purification of
liquid products of the decomposition of organic constituent of the household
rubbish. It was also developed the method of obtaining of an effective
coagulant from the wastes of aluminous production. This coagulant shown
positive effect for the purification of sewage of different origin and
in the method of destructive removal of a phenols from the phenol - containing
industrial effluents.
The considerable attention is devoted to the works connected with the
use of coagulants - flocculating agents of the "Syzol" series
in the processes of water purification. The wide investigations of their
activity in the processes of water and sewage purification are carried
out. One of the variants of reagents stated is a basic for the industrial
technology of purification of sewage from manganeze mining - concentrating
centre.
Additional information about subdivision.
Department ¹8 was organized in 1965 as a department of sulfolanes chemistry.
The priority direction of the subdivision was an investigation of the
reactivity of five - membered cyclic sulfolanes, the development of a
new methods of synthesis of their derivatives, detailed studying of the
chemical and biological properties of a new compounds and introduction
them into industry. During the work in this scientific field 2 doctoral
and 17 candidate dissertations were defended. 112 inventors certificates
of USSR and Ukraine and 3 foreign patents were prepared. 1 monograph,
5 rewiev papers and about 200 scientific publications were prepared for
this period. The department was headed by Dr. Bezmenova T. E. from 1965
to 1986, and by Dr. Grigoryev A. A. from 1986 to 2002.
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